• February 23, 2026
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Topics Covered


Introduction

Chemical Composition

Physical Properties

Mechanical Properties

Thermal Properties

Other Designations

Fabrication and Heat Treatment

     Machinability

     Forming

     Welding

     Heat Treatment

     Forging

     Hot Working

     Cold Working

     Annealing

     Tempering

     Hardening


Introduction


Alloy steels comprise different kinds of steels having compositions exceeding the limitations of B, C, Mn, Mo, Ni, Si, Cr, and Va set for carbon steels. They are designated by AISI four-digit numbers.


AISI 4320 alloy steel has high toughness and strength. It contains low carbon content to achieve good
welding characteristics.


Chemical Composition


The following table shows the chemical composition of AISI 4320 alloy steel.














Element

Content (%)

Iron, Fe

95.855 – 96.98

Nickel, Ni

1.65 – 2.00

Manganese, Mn

0.450 – 0.650

Chromium, Cr

0.400 – 0.600

Molybdenum, Mo

0.200 – 0.300

Carbon, C

0.170 – 0.220

Silicon, Si

0.150 – 0.300

Sulfur, S

 0.0400

Phosphorous, P

 0.0350


Physical Properties


The physical properties of AISI 4320 alloy steel are highlighted in the following table.







Properties

Metric

Imperial

Density

7.85 g/cm3

0.284 lb/in³

Melting point

1422°C

2590°F


Mechanical Properties


The mechanical properties of annealed AISI 4320 alloy steel are displayed in the following table.


















Properties

Metric

Imperial

Tensile strength

580 MPa

84100 psi

Yield strength

425 MPa

61600 psi

Bulk modulus (typical for steel)

140 GPa

20300 ksi

Shear modulus (typical for steel)

80 GPa

11600 ksi

Elastic modulus

190-210 GPa

27557-30458 ksi

Poisson’s ratio

0.27-0.30

0.27-0.30

Elongation at break (in 50 mm)

29%

29%

Reduction of area

58%

58%

Hardness, Brinell

163

163

Hardness, Knoop (converted from Brinell hardness)

184

184

Hardness, Rockwell B (converted from Brinell hardness)

84

84

Hardness, Vickers (converted from Brinell hardness)

170

170

Machinability (annealed and cold drawn. Based on 100 machinability for AISI 1212 steel)

60

60


Thermal Properties


The following table outlines the thermal properties of AISI 4320 alloy steel.







Properties

Metric

Imperial

Thermal expansion co-efficient (@ -18-95°C/-0.400-203°F, condition of specimen unknown)

11.3 µm/m°C

6.28 µin/in°F

Thermal conductivity (typical steel)

44.5 W/mK

309 BTU in/hr.ft².°F


Other Designations


Other designations that are equivalent to AISI 4320 alloy steel include:


  • ASTM A29 (4320)

  • ASTM A322 (4320)

  • ASTM A331 (4320)

  • ASTM A519 (4320)

  • ASTM A535 (4320)

  • ASTM A752 (4320)

  • SAE J1397 (4320)

  • SAE J404 (4320)

  • SAE J412 (4320)


Fabrication and Heat Treatment


Machinability


AISI 4320 alloy steel has good machinability in the annealed condition. However, it is difficult to machine this steel if it is hardened by heat treatment.


Forming


AISI 4320 alloy steel has good forming characteristic in the annealed condition.


Welding


AISI 4320 alloy steel has good weldability.


Heat Treatment


AISI 4320 alloy steel is normalized at 872°C (1650°F) before heat treatment. It is then heat treated at 816°C (1500°F) followed by quenching in oil and tempering to achieve desired hardness.


Forging


AISI 4320 alloy steel is forged at 1038 to 1205°C (1900 to 2200°F)


Hot Working


AISI 4320 alloy steel can be hot worked at 872 to 1205°C (1600 to 1900°F)


Cold Working


AISI 4320 alloy steel can be cold worked using by conventional methods in the annealed condition.


Annealing


AISI 4320 alloy steel is annealed at 872°C (1600°F) followed by slowly cooling in the furnace.


Tempering


AISI 4320 alloy steel can be tempered at 205 to 705°C (400 to 1300°F).


Hardening


AISI 4320 alloy steel can be hardened by cold working, or by teat treatment and tempering.



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